Write the balanced chemical equation for the following reaction using the oxidation number method:
Reaction of liquid hydrazine $(N_2H_4)$ with chlorate ion $(ClO_3^-)$ in basic medium produces nitric oxide gas $(NO)$ and chloride ion $(Cl^-)$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Step $1$: Assign oxidation numbers to the atoms undergoing change.
$N_2H_4$: $N$ is $-2$,$H$ is $+1$
$ClO_3^-$: $Cl$ is $+5$,$O$ is $-2$
$NO$: $N$ is $+2$,$O$ is $-2$
$Cl^-$: $Cl$ is $-1$
Step $2$: Identify oxidation and reduction half-reactions.
Oxidation: $N$ changes from $-2$ to $+2$ (loss of $4$ electrons per $N$ atom,total $8$ electrons per $N_2H_4$ molecule).
Reduction: $Cl$ changes from $+5$ to $-1$ (gain of $6$ electrons per $Cl$ atom).
Step $3$: Balance the electrons.
Multiply the oxidation half by $3$ and the reduction half by $4$ to balance the electrons ($24$ electrons transferred).
$3 N_2H_4 + 4 ClO_3^- \rightarrow 6 NO + 4 Cl^-$
Step $4$: Balance $O$ and $H$ atoms in basic medium.
Total $O$ on left: $12$. Total $O$ on right: $6$. Add $6 H_2O$ to the right side.
$3 N_2H_4 + 4 ClO_3^- \rightarrow 6 NO + 4 Cl^- + 6 H_2O$
Check $H$ atoms: Left side has $12 H$ $(3 \times 4)$. Right side has $12 H$ $(6 \times 2)$.
The equation is balanced: $3 N_2H_{4(l)} + 4 ClO_{3(aq)}^- \rightarrow 6 NO_{(g)} + 4 Cl_{(aq)}^- + 6 H_2O_{(l)}$

Explore More

Similar Questions

In an experiment,$50 \ mL$ of $0.1 \ M$ solution of a metal salt reacted with $25 \ mL$ of $0.1 \ M$ solution of sodium sulphite. The half-equation for the oxidation of sulphite ion is $SO_3^{2-}{(aq)} + H_2O_{(l)} \to SO_4^{2-}{(aq)} + 2H^{+}{(aq)} + 2e^-$. If the oxidation number of the metal in the salt was $3$,what would be the new oxidation number of the metal?

In the reaction $A^{-n_2} + x e^- \to A^{-n_1}$,the value of $x$ is:

Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$2NaI + MnO_2 + 2H_2SO_4 \to MnSO_4 + Na_2SO_4 + I_2 + 2H_2O$

In acidic medium,dichromate ion oxidises ferrous ion to ferric ion. If the gram molecular weight of potassium dichromate is $294 \ g$,its gram equivalent weight is $...$ grams.

How many moles of acidified $K_{2}Cr_{2}O_{7}$ are required to liberate $6$ moles of $I_{2}$ from an aqueous solution of $I^{-}$?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo